Synthesis of thermoresponsive block and graft copolymers via the combination of living cationic polymerization and RAFT polymerization using a vinyl ether-type RAFT agent
نویسندگان
چکیده
منابع مشابه
RAFT Polymerization of Vinyl Esters: Synthesis and Applications
This article is the first comprehensive review on the study and use of vinyl ester monomers in reversible addition fragmentation chain transfer (RAFT) polymerization. It covers all the synthetic aspects associated with the definition of precision polymers comprising poly(vinyl ester) building blocks, such as the choice of RAFT agent and reaction conditions in order to progress from simple to co...
متن کاملBlock copolymers containing organic semiconductor segments by RAFT polymerization.
Approaches to the synthesis of block copolymers containing organic semiconductor segments (polythiophene, perylene diimide) by RAFT polymerization have been explored. A method involving transformation of a vinyl derivative to a macro-RAFT agent provides for the synthesis of block copolymers which are joined by a short non-hydrolysable linkage.
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Exfoliated poly (Chloromethyl styrene-co-styrene)-g-polyacrylonitryle/organo- modified montmorillonite [P(CMSt-co-St)-g-PAN/O-MMT] nanocomposite was synthesized through solution intercalation method by using atom transfer and nitroxide mediated radical polymerization. At first, poly (chloromethyl styrene-costyrene) copolymer was synthesized by nitroxide - mediated “living” free radical polyme...
متن کاملControlled synthesis of thermoresponsive polymers derived from L-proline via RAFT polymerization.
Well-defined polymers derived from L-proline are synthesized using reversible addition-fragmentation chain transfer (RAFT) polymerization and the amino acid-based polymers exhibit thermosensitive phase separation at lower critical solution temperatures (LCST = 15-45 degrees C) in aqueous medium.
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ژورنال
عنوان ژورنال: Polymer
سال: 2014
ISSN: 0032-3861
DOI: 10.1016/j.polymer.2014.02.053